Difference Between Batteries and Cells

By Haijiang Lai

Owenr at SaftecEnergy

Table of Contents

What is a cell in a battery

A cell is the smallest electrochemical unit that produces electricity. It contains a negative electrode (anode), positive electrode (cathode), electrolyte, and a separator to keep the electrodes apart while ions move during charge and discharge.

Cells can be primary (single-use, e.g., alkaline, zinc-carbon) or secondary (rechargeable, e.g., Li-ion, LiFePO4, NiMH, lead-acid). Typical nominal voltages are 1.2 V (NiMH), 1.5 V (alkaline), 2.0 V (lead-acid cell), and 3.2–3.7 V (lithium chemistries). In short: a cell = one chemical “engine” that powers a circuit.

What is a battery and how is it different from a cell

A battery is one cell or several cells connected and packaged to deliver a target voltage and energy. Cells in series raise voltage; cells in parallel raise capacity. A practical battery also adds conductors, a case, and often a battery management system (BMS) to monitor and protect the pack (over-charge, over-discharge, temperature, and balancing).

Everyday speech calls a single AA a “battery,” but engineers treat it as one cell; a 12 V lead-acid or 51.2 V LiFePO4 home pack is a multi-cell battery.

Cell vs battery at a glance

TopicCellBattery
Core ideaOne electrochemical unitOne or more cells assembled
Typical useAA cell, 18650 cell12 V car battery, 51.2 V home pack
Voltage/CapacityFixed by chemistry & sizeSet by series/parallel layout + BMS

How do series and parallel cells change voltage and capacity

  • Series raises voltage: Vpack=n×Vcell; capacity (Ah) stays the same.
  • Parallel raises capacity: Cpack=m×Ccell; voltage stays the same.
  • Energy: E [Wh]=V×Ah.

Simple battery math you can reuse

12.8 V 100 Ah LFP (4S1P)
V=4×3.2=12.8 V; C=100 Ah; E=12.8×100=1280 Wh.

Double the capacity (4S2P)
Two identical 4S strings in parallel → V=12.8 V; C=200 Ah; E=2560Wh.

51.2 V 100 Ah rack battery (16S1P LFP)
V=16×3.2=51.2 V; C=100 Ah; E=5120 Wh=5.12 kWh.

High-voltage 102.4 V module (32S1P LFP)
V=32×3.2=102.4 V; if C=100 Ah then E=10.24kWh.

What is the difference between battery voltage and cell voltage

Names you’ll see

  • Cell voltage: the per-cell nominal value (typicals: LFP ≈ 3.2 V; NMC/Li-ion ≈ 3.6–3.7 V; NiMH ≈ 1.2 V; Alkaline ≈ 1.5 V; Lead-acid ≈ 2.0 V).
  • Battery (pack) voltage: the series count × per-cell voltage (e.g., 16 × 3.2 V = 51.2 V).

Nominal vs working range

  • Nominal is a label for comparison (e.g., 51.2 V).
  • Working range is what you measure in use (e.g., an LFP 16S pack might operate roughly 40–58 V depending on BMS limits and load).
  • Cut-off voltages (per-cell min/max) are enforced by the BMS to protect cells.

Voltage ≠ state of charge (SOC) in a straight line

  • LFP has a flat plateau, so voltage alone poorly predicts SOC in the mid-range.
  • Packs often need coulomb counting + periodic balance; voltage is more useful near the top/bottom of the curve.

C-rate, temperature, and internal resistance matter

  • Under high load (C-rate), measured voltage sags due to internal resistance (IR) and recovers at rest.
  • Cold temperatures increase IR → more sag; high temps can raise apparent voltage but stress the chemistry.

Where you measure from

  • A handheld meter across the pack reads pack voltage.
  • Cell-level voltage is read through a BMS or balance leads; uneven cells reduce usable capacity and trigger earlier cut-off.

Practical cheatsheet

  • Want more voltage? Add cells in series.
  • Want more runtime (Ah)? Add parallel strings.
  • Want safe, consistent packs? Use a BMS to watch per-cell limits and balance them.

What types of battery cells are used today

Cylindrical (e.g., 18650, 21700)

  • Pros: rugged can, great cycle consistency, mature automation.
  • Use: tools, laptops, e-bikes, some EV modules, portable ESS.

Prismatic (rectangular cans)

  • Pros: high packing density in racks/vehicles, fewer interconnects.
  • Use: home/industrial racks (e.g., 51.2 V modules), many EV/ESS systems.

Pouch (laminate foil)

  • Pros: very light/thin, flexible footprints.
  • Watch-outs: needs strong mechanical support and swelling management.
  • Use: consumer electronics, some EV and UAV packs.

Want a selection deep-dive (sizes, thermal behavior, cost, and use-case mapping)? Spin off a dedicated page (e.g., Types of Battery Cells: Cylindrical, Prismatic, and Pouch Compared) and link to it here.

FAQ

Is an AA battery a cell or a battery?
AA is a single cell. We often call it a battery in daily life, but technically it’s one cell.

How many cells make a 12 V, 24 V, or 48 V battery?

  • Lead-acid 12 V: 6 × 2.0 V cells in series ≈ 12.0 V.
  • LiFePO4 “12 V class”: 4S = 12.8 V.
  • LiFePO4 “24 V class”: 8S = 25.6 V.
  • LiFePO4 “48 V class”: 16S = 51.2 V (common for home/C&I).

Why does a 9 V battery use multiple small cells inside?
To reach ~9 V in a compact case: alkaline 6 × 1.5 V; NiMH 7 × 1.2 V (sold as 8.4 V nominal).

Can a single cell be called a battery in daily language?
Yes, but in engineering we reserve battery for an assembled unit (one or more cells plus connections/protection).

What is the difference between a primary cell and a secondary cell?
Primary = single-use (alkaline, zinc-carbon). Secondary = rechargeable (Li-ion, LiFePO4, NiMH, lead-acid).

What is the cell symbol vs the battery symbol in circuit diagrams?
A cell is one long + one short plate; a battery shows multiple plate pairs in a row.

Why do packs need a BMS when multiple cells are used?
The BMS monitors per-cell voltage/current/temperature, balances cells, and guards against over-charge, over-discharge, and short circuit.

How many cells are inside common batteries?

ItemWhat is it?Typical cells insideNominal voltageNotes
AA alkalineSingle primary cell1 × 1.5 V1.5 VCalled “AA battery” in daily life, but technically a cell.
AA NiMHSingle rechargeable cell1 × 1.2 V1.2 VReusable cell for cameras, toys.
18650 Li-ionSingle rechargeable cell1 × 3.6/3.7 V3.6–3.7 VCylindrical cell used in tools and laptops.
LiFePO4 cellSingle rechargeable cell1 × 3.2 V3.2 VCommon building block for energy storage.
9 V alkalineSmall battery6 × 1.5 V in series9.0 VInside are six tiny 1.5 V cells.
“9 V” NiMHRechargeable battery7 × 1.2 V in series8.4 VOften sold as 8.4 V; seven cells inside.
12 V lead-acidBattery6 × 2.0 V in series12.0 VCar starter and UPS.
12.8 V LFPBattery (4S)4 × 3.2 V in series12.8 VOften called “12 V LiFePO4.”
25.6 V LFPBattery (8S)8 × 3.2 V in series25.6 VTwo times the 12.8 V pack voltage.
51.2 V LFPBattery (16S)16 × 3.2 V in series51.2 VHome and C&I energy storage standard.
Laptop packBattery packMultiple 18650/21700 in series-parallel10.8–14.8 VIncludes BMS and sensors.
ESS rack packModule/pack16S/32S LFP, often paralleled51.2/102.4 VModule → rack → cabinet, with BMS and busbars.

As a supplier of energy storage products, my purpose in discussing this topic is to share with you how batteries are shaping different industries. If you are planning a project that requires Rack Battery, Lifepo4 Battery, or Home Storage Battery, contact us today to get a tailored solution.

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